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CHEMICAL ENGINEERING THERMODYNAMICS

Chemical Engineering Thermodynamics
For a constant volume process

dQ = dE + pdV
dE = CpdT
dE = CvdT
dW = pdV

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DQ = CpdT + Vdp
DQ = CvdT + PdV
DE = Tds - PdV

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Chemical Engineering Thermodynamics
For an exothremic reaction

Enthalpy change is zero
Both ΔH and ΔE are negative
Only internal energy change (ΔE) is negative
Only enthalpy change (ΔH) is negative

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Chemical Engineering Thermodynamics
For an ideal gas, the enthalpy

Decreases with rise in pressure
Increases with rise in pressure
Is independent of pressure
Is a path function

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Chemical Engineering Thermodynamics
Refrigerants commonly used for domestic refrigerators are

Freon-12
Propane
Ethyl chloride or methyle chloride
NH₃ or CO₂

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