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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a constant volume process

dW = pdV
dE = CvdT
dQ = dE + pdV
dE = CpdT

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Chemical Engineering Thermodynamics
Which of the following processes can not be made reversible even under ideal condition of operation?

Compression of air in a compressor
Expansion of steam in a turbine
Free expansion of a gas
All of these

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Chemical Engineering Thermodynamics
A system is said to be at equilibrium, if the entropy of the system has reached __________ value.

Zero
None of these
Minimum
Maximum

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Chemical Engineering Thermodynamics
The entropy change in a reversible isothermal process, when an ideal gas expands to four times its initial volume is

R log10 4
R loge 4
Cv log10 4
Cv loge 4

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Chemical Engineering Thermodynamics
"The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is

Henry's law
Called Lewis-Randall rule
None of these
The statement as per Gibbs-Helmholtz

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Chemical Engineering Thermodynamics
Cp - Cv = R is valid for __________ gases.

Very high pressure
Ideal
All
Very low temperature

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