Chemical Engineering Thermodynamics
The equation DU = Tds - PdV is applicable to infinitesimal changes occuring in

A closed system of constant composition
An open system with changes in composition
A closed system with changes in composition
An open system of constant composition

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Chemical Engineering Thermodynamics
In the reaction, H₂ +I₂ ⇋ 2HI, addition of an inert gas will

Increase the partial pressure of I₂
Not effect the equilibrium conditions
Increase the partial pressure of H₂
Increase the total pressure and hence shift the equilibrium towards the right

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