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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

A = H - TS
A = E - TS
None of these
A = H + TS

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DQ = CvdT + PdV
Tds = dE - PdV
DE = Tds - PdV
DQ = CpdT + Vdp

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Chemical Engineering Thermodynamics
__________ explains the equilibrium constant for any chemical reaction.

Henry's law
Law of mass action
None of these
Hess's law

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Chemical Engineering Thermodynamics
When pressure is applied on the system, ice ⟷ water, then

Evaporation of water will take place
More ice will be formed
More water will be formed
Equilibrium can not be established

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Chemical Engineering Thermodynamics
Fugacity of a component in an ideal gas mixture is euqal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at contant pressure and temperature __________ as its mole fraction increases.

Decreases exponentially
Increases
Remains constant
Decreases

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Chemical Engineering Thermodynamics
The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.

Pressure
Specific heat
Temperature
Volume

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