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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DE = Tds - PdV
DQ = CvdT + PdV
Tds = dE - PdV
DQ = CpdT + Vdp

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Chemical Engineering Thermodynamics
Heating of water under atmospheric pressure is an __________ process.

Isothermal
Isobaric
Isochoric
Adiabatic

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Chemical Engineering Thermodynamics
When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is

More in vapour phase
Zero in both the phases
More in liquid phase
Same in both the phases

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Chemical Engineering Thermodynamics
Air enters an adiabatic compressor at 300K. The exit temperature for a compression ratio of 3, assuming air to be an ideal gas (Y = Cp/Cv = 7/5) and the process to be reversible, is

300(33/7)
300(35/7)
300(33/5)
300(32/7)

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Chemical Engineering Thermodynamics
The thermodynamic law, PVy = constant, is not applicable in case of

Free expansion of an ideal gas
Ideal compression of air
Adiabatic compression of a perfect gas
Adiabatic expansion of steam in a turbine

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Chemical Engineering Thermodynamics
dW and dq are not the exact differential, because q and W are

Path functions
State functions
Intensive properties
Extensive properties

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