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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DE = Tds - PdV
DQ = CpdT + Vdp
DQ = CvdT + PdV

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Chemical Engineering Thermodynamics
When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the

Arrehenius hypothesis
Law of corresponding state
Kopp's rule
Le-Chatelier principle

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Chemical Engineering Thermodynamics
Entropy change for an irreversible isolated system is

∞
< 0
> 0

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Chemical Engineering Thermodynamics
Isentropic process means a constant __________ process.

Entropy
None of these
Enthalpy
Pressure

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Chemical Engineering Thermodynamics
Equilibrium constant of a reaction varies with the

None of these
Initial concentration of the reactant
Pressure
Temperature

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Chemical Engineering Thermodynamics
If two pure liquid constituents are mixed in any proportion to give an ideal solution, there is no change in

Enthalpy
Neither A nor B
Both A & B
Volume

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