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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Joule-Thomson co-efficient depends on the

Both A & B
Neither A nor B
Temperature
Pressure

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Chemical Engineering Thermodynamics
Internal energy of an ideal gas

Is independent of temperature
Decreases with increase in temperature
Increases with increase in pressure
None of these

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
-RT ln 0.5
-2 RT ln 0.5
2 RT

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂P)T = -(∂V/∂T)P
(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
The following heat engine produces power of 100000 kW. The heat engine operates between 800 K and 300 K. It has a thermal efficiency equal to 50% of that of the Carnot engine for the same temperature. The rate at which heat is absorbed from the hot reservoir is

100, 000 kW
160, 000 kW
320, 000 kW
200, 000 kW

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Chemical Engineering Thermodynamics
Isobaric process means a constant process.

Temperature
Volume
Entropy
Pressure

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