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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

2 RT
-RT ln 0.5
-2 RT ln 0.5
0.5 RT

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Chemical Engineering Thermodynamics
Which of the following is affected by the temperature?

Activity co-efficient
All of these
Fugacity
Free energy

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Chemical Engineering Thermodynamics
In an isothermal process on an ideal gas, the pressure increases by 0.5 percent. The volume decreases by about __________ percent.

0.25
0.75
0.5
1

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Chemical Engineering Thermodynamics
Consider the reaction, C + O₂ ⇋ CO₂ ;ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO₂ → C + O₂?

-94 kcal
> 94 kcal
< -94 kcal
+ 94 kcal

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Chemical Engineering Thermodynamics
For a given substance at a specified temperature, activity is __________ to fugacity.

Inversely proportional
Directly proportional
Equal
None of these

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Chemical Engineering Thermodynamics
Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is

Three times faster than Y
Faster than Y
Three times slower than Y
Slower than Y

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