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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following is affected by the temperature?

Free energy
All of these
Activity co-efficient
Fugacity

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Chemical Engineering Thermodynamics
For a cyclic process, a fixed ratio between heat and work

Always exists
Never exists
Is difficult to predict
May exist

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂V)T = (∂P/∂T)V
(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P

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Chemical Engineering Thermodynamics
In the equation PVn = constant, if the value of n = y = Cp/Cv, then it represents a reversible __________ process.

Polytropic
Isothermal
Isentropic
Adiabatic

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Chemical Engineering Thermodynamics
The fusion of a crystalline solid at its melting point to form a liquid at the same temperature is accompanied by

Decrease of entropy
Increase in enthalpy corresponding to absorption of heat
Decrease in enthalpy corresponding to evolution of heat
No change in enthalpy

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Chemical Engineering Thermodynamics
One ton of refrigeration capacity is equivalent to the heat removal rate of

200 BTU/minute
200 BTU/day
50 k cal/hr
200 BTU/hr

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