Chemical Engineering Thermodynamics
Which of the following is true for Virial equation of state?

Virial co-efficients are function of temperature only
For some gases, Virial equations and ideal gas equations are the same
Virial co-efficients are universal constants
Virial co-efficients

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature, pressure and liquid composition xi only
Temperature only
Temperature and pressure only
Temperature, pressure, liquid composition xi and vapour composition yi

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Chemical Engineering Thermodynamics
Free energy

Remains unchanged in reversible processes carried at constant temperature and pressure
Decreases in all spontaneous (or irreversible) processes
All of these
Change during a spontaneous process has a negative value

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