Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature, pressure and liquid composition xi only
Temperature only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature and pressure only

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Chemical Engineering Thermodynamics
The second law of thermodynamics states that

The energy change of a system undergoing any reversible process is zero
None of these
The total energy of system and surrounding remains the same
It is not possible to transfer heat from a lower temperature to a higher temperature

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