Chemical Engineering Thermodynamics
An irreversible process

Yields the maximum amount of work
Yields an amount of work less than that of a reversible process
Is an idealised visualisation of behaviour of a system
Is the analog of linear frictionless motion in machines

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
All of these
Volume in the liquid state is negligible compared with that in the vapour state
Vapour pressure is relatively low and the temperature does not vary over wide limits

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