Chemical Engineering Thermodynamics
Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg . K, entropy of saturated vapour = 7.2234 kJ/kg. K) The exit condition of steam is

Partially condensed vapour with quality of 0.9
Saturated vapour
Partially condensed vapour with quality of 0.1
Superheated vapour

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
Volume in the liquid state is negligible compared with that in the vapour state
All of these
Vapour pressure is relatively low and the temperature does not vary over wide limits

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Chemical Engineering Thermodynamics
Free energy

Change during a spontaneous process has a negative value
Decreases in all spontaneous (or irreversible) processes
Remains unchanged in reversible processes carried at constant temperature and pressure
All of these

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