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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
What is the value of ln y (where y = activity co-efficient) for ideal gases?

Negative
Unity
Infinity
Zero

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Chemical Engineering Thermodynamics
Compressibility factor-reduced pressure plot on reduced co-ordinates facilitates

Easier plotting
More accurate plotting
Covering of wide range
Use of only one graph for all gases

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Chemical Engineering Thermodynamics
For a constant volume process __________ by the system is used only to increase the internal energy.

Both A & B
Heat absorbed
Neither A nor B
Work done

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Chemical Engineering Thermodynamics
A gas mixture of three components is brought in contact with a dispersion of an organic phase in water. The degree of freedom of the system are

4
3
5
6

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ°+ R lnf
μ° + R/T lnf
μ° + T lnf
μ° + RT ln f

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

2
3
1

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