Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

Chemical Engineering Thermodynamics
The necessary and sufficient condition for equilibrium between two phases is

The temperature of each phase should be same
The chemical potential of each component should be same in the two phases
The concentration of each component should be same in the two phases
The pressure should be same in the two phases

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