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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a constant volume process __________ by the system is used only to increase the internal energy.

Neither A nor B
Work done
Both A & B
Heat absorbed

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Chemical Engineering Thermodynamics
One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is

30554
10373
4988.4
4364.9

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Chemical Engineering Thermodynamics
Trouton's ratio is given by (where λb, = molal heat of vaporisation of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K )

Tb/λb
λb/Tb
√(λb/Tb)
√(Tb/λb)

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂V)T = (∂P/∂T)V
(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
The main feature of Carnot refrigeration cycle is that, it

Transfers heat from high temperature to low temperature
None of these
Accomplishes the reverse effect of the heat engine
Does not need the addition of external work for its functioning

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Chemical Engineering Thermodynamics
No work is done by the system, when a reaction occurs at constant

Temperature
None of these
Volume
Pressure

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