Chemical Engineering Thermodynamics
Gibbs-Duhem equation

States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
None of these
Applies only to binary systems
Finds no application in gas-liquid equilibria involved in distillation

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Chemical Engineering Thermodynamics
Law of corresponding states says that

, two different gases behave similarly, if their reduced properties (i.e. P, V and T) are same
The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature
No gas can be liquified above the critical temperature, howsoever high the pressure may be
The molar heat of energy of gas at constant volume should be nearly constant (about 3 calories)

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