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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The first law of thermodynamics is a statement of conservation of

Momentum
Heat
Work
Energy

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Chemical Engineering Thermodynamics
Boiling of liquid is accompanied with increase in the

Vapor pressure
All of these
Specific Gibbs free energy
Specific entropy

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Chemical Engineering Thermodynamics
The value of Cp & Cv respectively for monoatomic gases in Kcal/kg Mole . °K are

5 & 3
1.987 & 0.66
3.987 & 1.987
0.66 & 1.987

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Chemical Engineering Thermodynamics
Boyle's law for gases states that

P ∝ V, at constant temperature & mass of the gas
P/V = constant, for any gas
P ∝ 1/V, when temperature is constant
P ∝ 1/V, when temperature & mass of the gas remain constant

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P

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Chemical Engineering Thermodynamics
Fugacity is a measure of the

Behaviour of ideal gases
Relative volatility of a mixture of two miscible liquids
Escaping tendencies of the same substance in different phases of a system
None of these

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