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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
__________ equation predicts the activity co-efficient from experimental data.

Both B & C
Van Laar
Lewis-Randall
Margules

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Chemical Engineering Thermodynamics
Fugacity is a measure of the

Relative volatility of a mixture of two miscible liquids
Escaping tendencies of the same substance in different phases of a system
None of these
Behaviour of ideal gases

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Chemical Engineering Thermodynamics
The activity of an ideal gas is numerically __________ its pressure.

More than
Less than
Data insufficient, can't be predicted
Equal to

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P

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Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

Negative
Positive
Zero
None of these

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Chemical Engineering Thermodynamics
In an irreversible process

Tds - dT + dW< 0
Tds = dE - dW = 0
Tds - dE + dW< 0
DE - dW - Tds = 0

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