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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The internal energy of an ideal gas is a function of its __________ only.

Volume
Temperature
Pressure
Molecular size

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Chemical Engineering Thermodynamics
For multicomponent multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases.

Chemical potential
Neither A nor B
Fugacity
Both A and B

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Chemical Engineering Thermodynamics
Equilibrium constant decreases as the temperature

Increases, for an endothermic reaction
Decreases, for an exothermic reaction
Increases, for an exothermic reaction
None of these

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + T lnf
μ° + RT ln f
μ° + R/T lnf
μ°+ R lnf

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Chemical Engineering Thermodynamics
All gases above its inversion temperature, in a throttling process will show

A heating effect
A cooling effect
Either A or C
No change in temperature

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Chemical Engineering Thermodynamics
For an exothremic reaction

Only enthalpy change (ΔH) is negative
Enthalpy change is zero
Only internal energy change (ΔE) is negative
Both ΔH and ΔE are negative

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