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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The internal energy of an ideal gas is a function of its __________ only.

Temperature
Volume
Molecular size
Pressure

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Chemical Engineering Thermodynamics
Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C.

300
540
327
270

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Chemical Engineering Thermodynamics
When a gas is expanded from high pressure region to low pressure region ; temper -ature change occurs. This phenomenon is related to the

Gibbs-Helmholtz equation
Gibbs-Duhem equation
Joule-Thomson effect
Third law of thermodynamics

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Chemical Engineering Thermodynamics
Degree of freedom of the system ice-water-vapour will be

0
3
2
1

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-RT ln 0.5
2 RT
-2 RT ln 0.5
0.5 RT

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Reversible isothermal volume change
Heating of an ideal gas
Cooling of a real gas
Expansion of a real gas

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