Chemical Engineering Thermodynamics
On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)S and the slope of the reversible isothermal line (∂P/∂V)T are related as (where, y = Cp/Cv) )

(∂P/∂V)S = y(∂P/∂V)T
(∂P/∂V)S = 1/y(∂P/∂V)T
(∂P/∂V)S = (∂P/∂V)T
(∂P/∂V)S = [(∂P/∂V)T]Y

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Vapour pressure is relatively low and the temperature does not vary over wide limits
All of these
Volume in the liquid state is negligible compared with that in the vapour state
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant

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