Chemical Reaction Engineering
For the liquid phase parallel reactions:R, rR = K?.CA2; E? = 80 KJ/moleS, rS = K?.CA ; E? = 120 KJ/mole The desired product is R. A higher selectivity of R will be achieved, if the reaction is conducted at

Low temperature in a PFR
High temperature in a PFR
High temperature in a CSTR
Low temperature in a CSTR

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA
ΔHA + ΔHR
E
E + ΔHA - ΔHR

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Chemical Reaction Engineering
The rate of the heterogenous catalytic reaction A(g) + B(g) ? C(g) is given by -rA = k.KA.pA.PB/(1 + KA.PA + Kc.pc), where KA and Kc are the adsorption equilibrium constants. The rate controlling step for this reaction isA. absorption of A.

Surface reaction between absorbed A and absorbed B
Absorption of A
Surface reaction between absorbed A and B in the gas phase
Surface reaction between A in the gas phase and absorbed B

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