Chemical Reaction Engineering
At a given value of E/R (ratio of activation energy and gas constant), the ratio of the rate constants at 500°K and 400°K is 2, if Arrhenious law is used. What will be this ratio, if transition state theory is used with the same value of E/R?

2.5
2
2.24
1.6

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Chemical Reaction Engineering
A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors.

Both conversion as well as concentration are same
Both the conversion as well as concentrations will be different
Conversion in both will be the same but concentrations will be different
None of these

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