Chemical Engineering Thermodynamics
Choose the condition that must be specified in order to liquify CO₂ (triple point for CO₂ is - 57°C and 5.2 atm).

Pressure and temperature must be kept below 5.2 atm. and - 57°C respectively
Pressure must be kept below 5.2 atm
Pressure must be kept below 5.2 atm. and temperature must be kept above 57°C
Temperature must be kept above - 57°C

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature only
Temperature, pressure and liquid composition xi only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature and pressure only

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