Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Saturated steam is used for steam distillation
Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Total pressure is less
Temperature is less

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Mass Transfer
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of

Vapour pressure of component A to the partial pressure of A
Vapour pressure of component A to the total pressure
Vapour pressure of component A to that of component B
Partial pressure of component A to the total pressure

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Mass Transfer
A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state,

The top and bottom compositions are unchanged with and without total reflux
Reboiler load and condenser load are minimum
Composition of vapors and that of liquid do not vary throughout the column
The top and bottom compositions correspond to the maximum enrichment available

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