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Mass Transfer

Mass Transfer
According to Poiseuille's law, the permeability for gas flow through a capillary is proportional to (where, μ = gas viscosity)

μ
√μ
1/μ
μ²

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Mass Transfer
In case of gases, the binary diffusivity is proportional to (where, P = pressure)

1/P
1/√P
√P
P

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Mass Transfer
Use of packed towers for distillation is generally limited to the

Vacuum distillation
High pressure operation
Small sizes
Multicomponent distillation

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Mass Transfer
Chemisorption compared to physical absorption has

Lower capacity of the solvent for the solute gas
Lower adsorption rate
Increased utilisation of stagnant zones of the liquid phase
None of these

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Mass Transfer
Weeping in a distillation column

Results due to very low gas velocity
Results due to very high gas velocity
Increases tray efficiency
Provides large interfacial surface for mass transfer

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Mass Transfer
The diffusivity (D) in a binary gas mixture is related to the pressure (P) as

D ∝ P0.5
D ∝ 1/P1.5
D ∝ 1/P
D ∝ 1/P0.5

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