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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The change in Gibbs freee energy for vaporisation of a pure substance is

Negative
May be positive or negative
Zero
Positive

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

Ax₁²
Ax₁
Ax₂
A . x₂²

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Chemical Engineering Thermodynamics
If we increase the pressure on a substance (which is at its triple point), then the triple point

Remains unchanged
Decreases
Increases
May increase or decrease ; depends on the substance

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Chemical Engineering Thermodynamics
Degree of freedom of the system ice-water-vapour will be

1
3
0
2

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Chemical Engineering Thermodynamics
Duringthe phase transition, __________ changes.

Temperature
All of these
Volume
Pressure

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Chemical Engineering Thermodynamics
Free energy change at equilibrium is

Indeterminate
Zero
Positive
Negative

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