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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a constant pressure reversible process, the enthalpy change (ΔH) of the system is

∫Cp.dT
∫Cv.dT
Cv.dT
Cp.dT

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

Ax₁
A . x₂²
Ax₁²
Ax₂

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Chemical Engineering Thermodynamics
Joule-Thomson Co-efficient at any point on the inversion curve is

+ ve
-ve
∞

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Chemical Engineering Thermodynamics
Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is

Zero
Infinity
Positive
Negative

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Chemical Engineering Thermodynamics
Entropy of the system decreases, when

Both B & C
Snow melts into water
Water is converted into ice
A gas expands spontaneously from high pressure to low pressure

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Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

Negative
None of these
Positive
Zero

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