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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Pick out the correct equation relating 'F' and 'A'.

F = A - TS
F = E + A
F = A + TS
F = A + PV

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

3
1
2

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Chemical Engineering Thermodynamics
Compressibility factor of a gas is

Unity, if it follows PV = nRT
Not a function of its pressure
Not a function of its temperature
Not a function of its nature

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Chemical Engineering Thermodynamics
At normal boiling point, molar entropy of vaporisation is __________ Joule/K°.mole.

72
92
142
192

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Chemical Engineering Thermodynamics
When a gas in a vessel expands, its internal energy decreases. The process involved is

Adiabatic
Reversible
Isothermal
Irreversible

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Chemical Engineering Thermodynamics
The efficiency of a Carnot heat engine operating between absolute temperatures T₁ and T₂ (when, T₁ > T₂) is given by (T₁ - T₂)/T₁. The co-efficient of performance (C.O.P.) of a Carnot heat pump operating between T₁ and T₂ is given by

T₂/(T₁-T₂)
T₁/(T₁-T₂)
T₂/R1
T₁/T₂

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