Chemical Reaction Engineering
In which of the following reactions, thee-quilibrium will shift to the right, if the total pressure is increased?

N₂ + O₂ ⇋ 2NO
H₂ + I₂ ⇋ 2HI
H₂ + Cl₂ ⇋ 2HCl
N₂O₄ ⇋ 2 NO₂

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Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
Langmuir
None of these
There is no dynamic equilibrium between successive layer

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Chemical Reaction Engineering
For a tubular reactor with space time 'τ' and residence time 'θ', the following statement holds good.

τ = θ , when the fluid density changes in the reactor
τ and θ are always equal
τ = θ , for a non-isothermal reactor
τ = θ , for an isothermic tubular reactor in which the density of the process fluid is constant

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