Chemical Engineering Thermodynamics
In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

Unpredictable; depends on the particular reaction
Same
More
Less

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Chemical Engineering Thermodynamics
On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)S and the slope of the reversible isothermal line (∂P/∂V)T are related as (where, y = Cp/Cv) )

(∂P/∂V)S = (∂P/∂V)T
(∂P/∂V)S = y(∂P/∂V)T
(∂P/∂V)S = [(∂P/∂V)T]Y
(∂P/∂V)S = 1/y(∂P/∂V)T

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Chemical Engineering Thermodynamics
The third law of thermodynamics states that the

Heat capacity of a crystalline solid is zero at absolute zero temperature
None of these
Heat transfer from low temperature to high temperature source is not possible without external work
Gases having same reduced properties behave similarly

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