Chemical Engineering Thermodynamics
PVy = constant, holds good for an isentropic process, which is

Isothermal and irreversible
Adiabatic and irreversible
Reversible and isothermal
Reversible and adiabatic

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Chemical Engineering Thermodynamics
An irreversible process

Is the analog of linear frictionless motion in machines
Is an idealised visualisation of behaviour of a system
Yields the maximum amount of work
Yields an amount of work less than that of a reversible process

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