Chemical Engineering Thermodynamics
In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants )

Pressure has no effect on equilibrium, when Δn = 0
Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero)
Addition of inert gas favours the forward reaction, when Δx is positive
All of these

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature only
Temperature, pressure and liquid composition xi only
Temperature and pressure only
Temperature, pressure, liquid composition xi and vapour composition yi

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