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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a cyclic process, a fixed ratio between heat and work

Never exists
Is difficult to predict
May exist
Always exists

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = nR ln (V₂/V₁) + nCv ln (T₂/T₁) is valid for

Reversible isothermal volume change
Cooling of a substance
Heating of a substance
Simultaneous heating and expansion of an ideal gas

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Chemical Engineering Thermodynamics
After throttling, gas temperature

Increases
May increase or decrease ; depends on the nature of the gas
Decreases
Remains same

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Chemical Engineering Thermodynamics
For spontaneous changes in an isolated system (S = entropy)

Ds <0
Ds = Constant
Ds = 0
Ds > 0

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Chemical Engineering Thermodynamics
Entropy change in case of reversible adiabatic process is

Maximum
Zero
Minimum
Indeterminate

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Chemical Engineering Thermodynamics
With increase in pressure (above atmospheric pressure), the Cp of a gas

First decreases and then increases
Decreases
Remains unchanged
Increases

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