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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
If heat contents of CH₄, C₂H₄ and C₃H₈ are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH₄(g) + C₂H₄(g) ⇋ C₃H₈(g) will be __________ Kcal.

-55.2
-30.2
55.2
-19.4

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Chemical Engineering Thermodynamics
Which is not a refrigerant?

SO₂
CCl₂F₂
NH₃
C₂H₄Cl₂

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Chemical Engineering Thermodynamics
In any spontaneous process, the __________ free energy decreases.

Helmholtz
Both of the listed here
Gibbs
Neither A nor B

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Chemical Engineering Thermodynamics
The efficiency of a Carnot heat engine operating between absolute temperatures T₁ and T₂ (when, T₁ > T₂) is given by (T₁ - T₂)/T₁. The co-efficient of performance (C.O.P.) of a Carnot heat pump operating between T₁ and T₂ is given by

T₁/T₂
T₂/(T₁-T₂)
T₂/R1
T₁/(T₁-T₂)

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Chemical Engineering Thermodynamics
A gas shows deviation from ideal behaviour at

High temperature and high pressure
Low pressure and high temperature
Low temperature and high pressure
Low pressure and low temperature

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Chemical Engineering Thermodynamics
In case of the decomposition of hydroiodic acid (2HI ⇋ H₂ + I₂), addition of H₂ (at equilibrium condition) will

Increase the partial pressure of I₂
Decrease the partial pressure of HI
None of these
Diminish the degree of dissociation of HI

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