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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a spontaneous process, free energy

Increases
And entropy both decrease
Decreases whereas the entropy increases
Is zero

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

Ax₁
Ax₁²
Ax₂
A . x₂²

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Chemical Engineering Thermodynamics
The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

Either A, B or C
Expands
Contracts
Does not change in volume

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Chemical Engineering Thermodynamics
A Carnot cycle consists of the following steps :

Two isothermals and two isochorics
Two isothermals and two isentropics
Two isobarics and two isothermals
Two isochorics and two isobarics

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Chemical Engineering Thermodynamics
Specific __________ does not change during phase change at constant temperature and pressure.

Gibbs energy
Entropy
Internal energy
Enthalpy

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Chemical Engineering Thermodynamics
An ideal liquid refrigerant should

Both A and B
Not have unduly high vapour pressure at the condenser temperature
Not have a subatmospheric vapour pressure at the temperature in the refrigerator coils
Have low specific heat

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