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CHEMICAL ENGINEERING THERMODYNAMICS

Chemical Engineering Thermodynamics
During Joule-Thomson expansion of gases

None of these
Entropy remains constant
Enthalpy remains constant
Temperature remains constant

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Chemical Engineering Thermodynamics
The entropy change in a reversible isothermal process, when an ideal gas expands to four times its initial volume is

Cv loge 4
R loge 4
Cv log10 4
R log10 4

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Chemical Engineering Thermodynamics
As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches

Unity
Zero
An indeterminate value
Infinity

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-2 RT ln 0.5
2 RT
0.5 RT
-RT ln 0.5

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Replaced by chemical potential which is more in vapour phase
Same in both the phases
More in liquid phase
More in vapour phase

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