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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
At absolute zero temperature, the __________ of the gas is zero.

Volume
None of these
Mass
Pressure

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Chemical Engineering Thermodynamics
For an exothremic reaction

Only internal energy change (ΔE) is negative
Only enthalpy change (ΔH) is negative
Both ΔH and ΔE are negative
Enthalpy change is zero

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Chemical Engineering Thermodynamics
The equation Tds = dE - PdV applies to

Open as well as closed systems
Both B and C
Single phase fluid of constant composition
Single phase fluid of varying composition

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Chemical Engineering Thermodynamics
Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is

1
3
2

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
2 RT
-RT ln 0.5
-2 RT ln 0.5

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Chemical Engineering Thermodynamics
The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

Does not change in volume
Expands
Contracts
Either A, B or C

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