Chemical Reaction Engineering
Promoter.

Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals
All of these
Initiates a chemical reaction and is a catalyst by itself
Atlers the position of equilibrium in a reversible reaction

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Chemical Reaction Engineering
In Langmuir treatment of adsorption,

All the adsorption does not take place by the same mechanism
Whole surface of the catalyst is essentially uniform and the adsorbed molecule has no effect on the rate of adsorption per site
Extent of adsorption is more than one complete monomolecular layer on the surface
Whole surface of the catalyst does not have the same activity for adsorption and there is attraction between the adsorbed molecule

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Desorption of C
Surface reaction between A in the gas phase and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between absorbed A and absorbed B

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