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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure

Decreases linearly
Increases
Remains same
Decreases

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

1
3
2

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-2 RT ln 0.5
-RT ln 0.5
2 RT
0.5 RT

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = nR ln (V₂/V₁) + nCv ln (T₂/T₁) is valid for

Reversible isothermal volume change
Heating of a substance
Simultaneous heating and expansion of an ideal gas
Cooling of a substance

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Chemical Engineering Thermodynamics
A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.

Open
Isolated
None of these
Closed

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Chemical Engineering Thermodynamics
Compressibility factor-reduced pressure plot on reduced co-ordinates facilitates

Easier plotting
Use of only one graph for all gases
Covering of wide range
More accurate plotting

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