Chemical Engineering Thermodynamics
When a gas is expanded from high pressure region to low pressure region ; temper -ature change occurs. This phenomenon is related to the

Gibbs-Helmholtz equation
Gibbs-Duhem equation
Joule-Thomson effect
Third law of thermodynamics

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Chemical Engineering Thermodynamics
Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which

None of these
Mutual solubility of the two liquids shows a decreasing trend
Two liquids are completely separated into two layers
A homogeneous solution (say of phenol water) is formed

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Chemical Engineering Thermodynamics
The second law of thermodynamics states that

The energy change of a system undergoing any reversible process is zero
It is not possible to transfer heat from a lower temperature to a higher temperature
None of these
The total energy of system and surrounding remains the same

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