Stoichiometry
Unrestrained expansion of an ideal gas does not result in its cooling due to the reason that the gas molecules

Do not lose energy on collision
Are above the inversion temperature
Do not exert attractive force on each other
Do work equal to loss in kinetic energy

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

All of these
Molal latent heat of vaporisation is constant within the limited temperature range
Volume in the liquid state is negligible compared with that in the vapor state
Vapor follows the ideal gas law

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