Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Of very large activation energy of many bodies
Many body collisions are not favoured energetically
Of low probability of many body collisions
Of requirement of very large concentration for such reactions

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Chemical Reaction Engineering
"A spherical porous catalyst particle of radius R is subjected to reactant A which reacts to form B by a zero order surface reaction A → B. Film mass transfer resistance is negligible and pore diffusion of A is rate controlling. The effectiveness factor of the catalyst is reported as 7/8. Which of the following statement is true?A. Inner catalyst core of radius R/8 does not participate in reaction."

Inner catalyst core of radius R/2 does not participate in reaction
Inner catalyst core of radius R/8 does not participate in reaction
Ffectiveness factor for a zero order reaction can not be 7/8 as it must always be 1
Inner catalyst core of radius 7R/8 does not participate in reaction

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Chemical Reaction Engineering
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Fast reactions in catalyst of small pore diameter
Slow reactions in catalyst of large pore diameter
Slow reactions in catalyst of small pore diameter
Fast reaction in catalyst of large pore diameter

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