Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Many body collisions are not favoured energetically
Of low probability of many body collisions
Of requirement of very large concentration for such reactions
Of very large activation energy of many bodies

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Chemical Reaction Engineering
For a tubular reactor with space time 'τ' and residence time 'θ', the following statement holds good.

τ = θ , when the fluid density changes in the reactor
τ = θ , for an isothermic tubular reactor in which the density of the process fluid is constant
τ and θ are always equal
τ = θ , for a non-isothermal reactor

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