Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E
ΔHA + ΔHR
E + ΔHA - ΔHR
E + ΔHA

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Chemical Reaction Engineering
Which of the following is the optimum operating condition for an exothermic reversible reaction taking place in a plug-flow reactor?

Very high temperature should be used throughout the reaction
None of these
Temperature should be high in the beginning and decreased towards the end of the reaction
Very low temperature should be used throughout the reaction

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