Stoichiometry
The heat capacity of a solid compound is calculated from the atomic heat capacities of its constituent elements with the help of the

Kopp's rule
Antonie equation
Kistyakowsky equation
Trouton's rule

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

The component molecules are non polar and are of almost equal size
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
No component is concentrated at the surface of the solution
The attractive forces between like and unlike molecules are almost equal

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