Chemical Engineering Thermodynamics
The expression, ΔG = nRT .In P₂/P₁ , gives the free energy change

With pressure changes at constant temperature
During cooling of an ideal gas
Under reversible isothermal volume change
During heating of an ideal gas

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

All of these
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
Volume in the liquid state is negligible compared with that in the vapour state
Vapour pressure is relatively low and the temperature does not vary over wide limits

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