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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The compressibility factor of a gas is given by (where, V₁ = actual volume of the gas V₂ = gas volume predicted by ideal gas law )

V₁/V₂
V₁.V₂
V₂/V₁
V₁-V₂

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Chemical Engineering Thermodynamics
Trouton's ratio is given by (where λb, = molal heat of vaporisation of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K )

√(Tb/λb)
Tb/λb
λb/Tb
√(λb/Tb)

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Chemical Engineering Thermodynamics
The standard Gibbs free energy change of a reaction depends on the equilibrium

All of these
Temperature
Pressure
Composition

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Chemical Engineering Thermodynamics
Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in

Decreased COP
Increased COP
Increased or decreased COP ; depending upon the type of refrigerant
Same COP

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Chemical Engineering Thermodynamics
At absolute zero temperature, all substances have the same

Crystalline structure
None of these
Heat capacity
Entropy

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Chemical Engineering Thermodynamics
As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches

Infinity
Zero
An indeterminate value
Unity

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