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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

< 3
< 1
> 2
> 1

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Chemical Engineering Thermodynamics
The equation relating E, P, V and T which is true for all substanes under all conditions is given by (∂E/∂V)T = T.(∂P/∂T)H - P . This equation is called the

Thermodynamic equation of state
Maxwell
Redlich-Kwong equation of state
Equation of state

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + R/T lnf
μ° + RT ln f
μ° + T lnf
μ°+ R lnf

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Chemical Engineering Thermodynamics
Which of the following processes can not be made reversible even under ideal condition of operation?

Compression of air in a compressor
All of these
Free expansion of a gas
Expansion of steam in a turbine

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Chemical Engineering Thermodynamics
Which of the following is a thermodynamic property of a system?

Entropy
Temperature
Mass
Concentration

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Chemical Engineering Thermodynamics
If we increase the pressure on a substance (which is at its triple point), then the triple point

Remains unchanged
May increase or decrease ; depends on the substance
Increases
Decreases

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