Spectroscopy
Vibrational spectroscopy is

a class of spectroscopic techniques which analyzes molecular motions
an Infrared spectroscopy
a large mass on a weak spring
a flashlight through a prism and shake it

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Spectroscopy
Why are rotational transitions of little use to a spectroscopist?

Because, in liquids and solids, spectral lines corresponding to rotational transitions are broadened as the result of molecular collisions and other interactions
Because the energy required to induce a rotational transition is so small that it cannot be measured
Because rotational transitions are extremely rare
All of these

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