Chemical Reaction Engineering
In which of the following gaseous phase reversible reactions, the product yield can not be increased by the application of high pressure?

N₂ + O₂ ⇋ 2NO
2SO₂ + O₂ ⇋ 2SO₃
PCl3 + Cl₂ ⇋ PCl5
N + 3H₂ ⇋ 2NH₃

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA
E + ΔHA - ΔHR
E
ΔHA + ΔHR

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