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Chemical Reaction Engineering

Chemical Reaction Engineering
In which of the following gaseous phase reactions, the equilibrium of the reaction remains unaffacted by pressure changes ?

2O? ? 3O?
N? + O? ? 2NO
2NO? ? N?O?
2SO? + O? ? 2SO?

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Chemical Reaction Engineering
The vessel dispersion number (D/μL) for plug flow is

500
750
∞

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Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3 = (K₁.K₂)2
K3 = K₁.K₂
K3(K₁+K₂)/2
K3 = (K₁.K₂)0.5

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Chemical Reaction Engineering
Differential method for analysing the kinetic data is used

None of these
For testing complicated mechanisms
When the data are scattered
When rate expressions are very simple

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Chemical Reaction Engineering
The rate of a gas phase reaction is given by K . CA . CB. If the volume of the reaction vessel is reduced to l/4th of its initial volume, then the reaction rate compared to the original rate will be __________ times.

16
8
4
2

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Chemical Reaction Engineering
Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as

k ∝ T1.5
k ∝ T
k ∝ exp(-E/RT)
k ∝ √T

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